YAN Gang, LIU Wei, LUO Junhui, GU Kaikai, LI Cong, YANG Li, ZHOU Yichun. CMAS Corrosion Behavior of YSZ Thermal Barrier Coatings Prepared by PS–PVD [J]. Aeronautical Manufacturing Technology, 2023, 66(17): 57-63.
YAN Gang, LIU Wei, LUO Junhui, GU Kaikai, LI Cong, YANG Li, ZHOU Yichun. CMAS Corrosion Behavior of YSZ Thermal Barrier Coatings Prepared by PS–PVD [J]. Aeronautical Manufacturing Technology, 2023, 66(17): 57-63. DOI: 10.16080/j.issn1671-833x.2023.17.057.
CMAS Corrosion Behavior of YSZ Thermal Barrier Coatings Prepared by PS–PVD
Thermal barrier coatings (TBCs) are widely used in the hot end components of advanced aero-engines
effectively prolong the service life of the hot end components
and become essential thermal protection materials for advanced aero-engines. However
in the process of service
some atmospheric sediments CMAS became molten after heating and adsorbed on the surface of the thermal barrier coating
and penetrated into the coating along the defects such as pores and cracks
leading to premature failure of the coating. YSZ thermal barrier coating was prepared by plasma spraying–physical vapor deposition (PS–PVD). XRD
SEM and other characterization methods were used to characterize the phase composition and microstructure of the coating with different corrosion time. The results show that YSZ coatings undergo phase transition after CMAS corrosion at 1250 ℃ . With the increase of corrosion time
CMAS sediments will penetrate into the interior along the columnar crystal gap of the thermal barrier coating
resulting in loose coating structure
columnar crystal fracture phenomenon in the upper region of the ceramic layer
and the coating macro performance is part of the ceramic layer spalling. After 8 h of corrosion
columnar crystals appear in some areas of the ceramic layer and peel off from the bonding layer. The penetration depth of CMAS increases with the increase of corrosion time. The penetration rate of CMAS is relatively fast within 3 h of corrosion
but becomes relatively slow after 3 h of corrosion.