LI Jin, HE Peigang. Effect of Phosphate Composition on Mechanical and Dielectric Properties of Quartz Fiber-Reinforced Phosphate Composites[J]. Aeronautical Manufacturing Technology, 2024, 67(14): 83-92.
LI Jin, HE Peigang. Effect of Phosphate Composition on Mechanical and Dielectric Properties of Quartz Fiber-Reinforced Phosphate Composites[J]. Aeronautical Manufacturing Technology, 2024, 67(14): 83-92. DOI: 10.16080/j.issn1671-833x.2024.14.083.
Effect of Phosphate Composition on Mechanical and Dielectric Properties of Quartz Fiber-Reinforced Phosphate Composites
The effects of P/Al ratio and Cr/Al ratio on the phase composition
microstructure
mechanical properties and dielectric properties of quartz fiber-reinforced phosphate composites were investigated. The results show that the phase composition of the phosphate matrix is mainly composed of Berlinite phase
low-temperature quartz type AlPO
4
and unreacted α–Al
2
O
3
and the composition ratio and microstructure of the matrix phase are influenced by the P/Al ratio and Cr/P ratio. When P/Al=4.1 and Cr/P=0.04
the composites have the best mechanical properties
with t
ensile strength of 108.6 MPa
bending strength of 135.3 MPa and fracture toughness K
ⅠC
of 6.6 MPa·m
1/2
and the composites exhibit the plastic fracture characteristics of weak bonding interface. It is analyzed that at this time the matrix contains more Al(H
2
PO
4
)
3
phase with good bonding properties
and the matrix exhibits a smooth planar-like structure
which is conducive to the formation of a complete and continuous good interfacial layer between the matrix and the fiber. In addition
the dielectric properties of the materials are greatly affected by the Cr content
except for Cr/P=0.08 materials
the dielectric properties of the prepared materials can meet the performance requirements of high-temperature wave-transparent materials