周阳,李文韬,王博,史志武,李淑苹,梁加淼,周菲,王俊,孙宝德. 微量元素Zr在K417/K417G铸造镍基高温合金中的分布状态与作用机理研究[J]. 航空制造技术, 2024, 67(23/24): 46-57. ZHOU Yang, LI Wentao, WANG Bo, SHI Zhiwu, LI Shuping, LIANG Jiamiao, ZHOU Fei, WANG Jun, SUN Baode. Investigations on Segregations and Functioning Mechanisms of Minor Element Zr in K417/K417G Cast Nickel-Based Superalloys[J]. Aeronautical Manufacturing Technology, 2024, 67(23/24): 46-57.
ZHOU Yang, LI Wentao, WANG Bo, et al. Investigations on Segregations and Functioning Mechanisms of Minor Element Zr in K417/K417G Cast Nickel-Based Superalloys[J]. Aeronautical Manufacturing Technology, 2024, 67(23/24).
周阳,李文韬,王博,史志武,李淑苹,梁加淼,周菲,王俊,孙宝德. 微量元素Zr在K417/K417G铸造镍基高温合金中的分布状态与作用机理研究[J]. 航空制造技术, 2024, 67(23/24): 46-57. ZHOU Yang, LI Wentao, WANG Bo, SHI Zhiwu, LI Shuping, LIANG Jiamiao, ZHOU Fei, WANG Jun, SUN Baode. Investigations on Segregations and Functioning Mechanisms of Minor Element Zr in K417/K417G Cast Nickel-Based Superalloys[J]. Aeronautical Manufacturing Technology, 2024, 67(23/24): 46-57. DOI: 10.16080/j.issn1671-833x.2024.23/24.046.
ZHOU Yang, LI Wentao, WANG Bo, et al. Investigations on Segregations and Functioning Mechanisms of Minor Element Zr in K417/K417G Cast Nickel-Based Superalloys[J]. Aeronautical Manufacturing Technology, 2024, 67(23/24). DOI: 10.16080/j.issn1671-833x.2024.23/24.046.
Investigations on Segregations and Functioning Mechanisms of Minor Element Zr in K417/K417G Cast Nickel-Based Superalloys
As modern aircraft engines advance towards higher thrust-to-weight ratios
increased reliability
and longer lifespans
greater demands are placed on the temperature-bearing capacity and comprehensive service performance of superalloys in hot-end components of engines. In the preparation process of cast superalloys
minor alloying elements in the master alloy play a crucial role in optimizing the microstructure and mechanical properties. This paper focuses on the extensively used K417 and K417G casting superalloys
analyzing the function mechanisms of typical minor element Zr and character
ization methods of its distribution features. The analysis mainly includes the influence of minor element Zr on the solidification characteristics
microstructure
and stress-rupture life of casting superalloys. Research shows that the addition of Zr element can effectively reduce the liquidus and solidus temperatures of the alloy and promote the formation of eutectic structure. At the same time
the addition of an appropriate amount (mass fraction of 0.07%–0.09%) of Zr can help improve the stress-rupture life of K417G superalloys; In addition
the time-of-flight secondary-ion-mass-spectrometry and transmission electron microscopy analysis results show that the Zr element is distributed along the interface between the eutectics and alloy matrix in the form of Ni
11
Zr
9
intermetallic compounds
instead of being only enriched at the grain boundaries as previously believed. The above research provides theoretical basis and data support for the control of minor alloying element content in cast superalloys.