1. 中国航发沈阳黎明航空发动机有限责任公司技术中心,沈阳,110043
2. 北京航空航天大学,北京,100191
3. 空装驻沈阳地区第二军事代表室,沈阳,110043
4. 中国航发沈阳黎明航空发动机有限责任公司热表处理厂,沈阳,110043
纸质出版:2022
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李汉运,王博,彭新,杨霖,袁福河. 湿吹砂电弧离子镀 AlSiY 涂层的抗高温腐蚀性能[J]. 航空制造技术, 2022, 65(15): 75-81.
LI Hanyun,WANG Bo,PENG Xin,YANG Lin,YUAN Fuhe. High Temperature Corrosion Resistance of Wet Grit Blasted AIP AlSiY Coating[J]. Aeronautical Manufacturing Technology, 2022, 65(15): 75-81.
李汉运,王博,彭新,杨霖,袁福河. 湿吹砂电弧离子镀 AlSiY 涂层的抗高温腐蚀性能[J]. 航空制造技术, 2022, 65(15): 75-81. DOI: 10.16080/j.issn1671-833x.2022.15.075.
LI Hanyun,WANG Bo,PENG Xin,YANG Lin,YUAN Fuhe. High Temperature Corrosion Resistance of Wet Grit Blasted AIP AlSiY Coating[J]. Aeronautical Manufacturing Technology, 2022, 65(15): 75-81. DOI: 10.16080/j.issn1671-833x.2022.15.075.
为解决和减轻航空发动机及燃气轮机高压涡轮叶片合金表面的高温腐蚀问题,采用空心阴极电弧离子镀技术在DZ22定向凝固镍基高温合金表面沉积AlSiY涂层。结果表明,沉积的 AlSiY 涂层经过高温真空扩散热处理后由表面层、中间层和薄的内扩散层组成,为β–NiAl 单相金属间化合物合金,具有高活度扩散渗铝涂层的组织特征。热腐蚀热重分析以及对涂层截面形貌观察结果说明湿吹砂处理显著改善了涂层抗涂盐及燃气高温腐蚀性能。未湿吹砂处理的 AlSiY扩散涂层表面的涂盐和燃气热腐蚀产物皆为Al
2
O
3
和NiAl
2
O
4
,氧化膜较厚且涂层内有孔洞形成,涂层几乎全部退化成了γ′–Ni
3
Al相。经过湿吹砂处理的 AlSiY扩散涂层的涂盐和燃气热腐蚀产物都以Al
2
O
3
为主,生成的氧化铝膜薄而致密,显著改善涂层的抗高温热腐蚀性能,从而延长涂层的使用寿命。
AlSiY coating was deposited on the directionally solidified DZ22 superalloy using an arc ion plating technique in an aim to resolve or alleviate the high temperature corrosion damage of high pressure turbine blades for aero-engines and gas turbine engines. The attained results demonstrate that the AlSiY coating deposited and vacuum diffusion heat treated at a high temperature consists of an outer
an intermediate and a thin inner diffusion layer
which is typical of a high activity aluminide diffusion coating composed of the single β–NiAl intermetallic phase. The results of thermogravimetric analyses and examinations of cross sections demonstrated that the wet gr
it blasting process improves significantly the corrosion resistance of the AlSiY coating under salt film and hot-gas conditions. A thick oxide scale developed on the as-diffusion heat treated coating consists primarily of Al
2
O
3
and NiAl
2
O
4
corrosion products under salt film and hot-gas corrosion conditions
and most of the coating degenerated into the γ′–Ni
3
Al phase with some pores formed inside. Wet grit blasting of the heat treated AlSiY coating is desirable to promote the selective oxidation of aluminium
chromium elements and formation of a thin
denser alumina scale under both corrosion conditions
thereby enhance remarkably the high temperature corrosion resistance and prolong the service life of the arc ion plated AlSiY coating.
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