1. 中国科学技术大学,沈阳,110016
2. 中国科学院金属研究所师昌绪先进材料创新中心,沈阳,110016
纸质出版:2023
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王伟,武姣姣,沈明礼,朱圣龙. 氧掺杂对NiCrAlYN 纳米金属陶瓷涂层抗氧化性能的影响[J]. 航空制造技术, 2023, 66(1/2): 46-52. WANG Wei, WU Jiaojiao, SHEN Mingli, ZHU Shenglong. Effect of Oxygen Doping on High-Temperature Oxidation Resistance of NiCrAlYN Coatings[J]. Aeronautical Manufacturing Technology, 2023, 66(1/2): 46-52.
WANG Wei, WU Jiaojiao, SHEN Mingli, et al. Effect of Oxygen Doping on High-Temperature Oxidation Resistance of NiCrAlYN Coatings[J]. Aeronautical Manufacturing Technology, 2023, 66(1/2).
王伟,武姣姣,沈明礼,朱圣龙. 氧掺杂对NiCrAlYN 纳米金属陶瓷涂层抗氧化性能的影响[J]. 航空制造技术, 2023, 66(1/2): 46-52. WANG Wei, WU Jiaojiao, SHEN Mingli, ZHU Shenglong. Effect of Oxygen Doping on High-Temperature Oxidation Resistance of NiCrAlYN Coatings[J]. Aeronautical Manufacturing Technology, 2023, 66(1/2): 46-52. DOI: 10.16080/j.issn1671-833x.2023.01/02.046.
WANG Wei, WU Jiaojiao, SHEN Mingli, et al. Effect of Oxygen Doping on High-Temperature Oxidation Resistance of NiCrAlYN Coatings[J]. Aeronautical Manufacturing Technology, 2023, 66(1/2). DOI: 10.16080/j.issn1671-833x.2023.01/02.046.
研究了不同O 含量掺杂对NiCrAlYN 纳米金属陶瓷涂层在1100 ℃下抗氧化性能的影响。采用多弧离子镀设备,分别在0、10 sccm、20 sccm O
2
流量下制备得到3 种不同O 含量的涂层。经1100 ℃、300 h 的高温测试后,3 组样品表面均生成了α–Al
2
O
3
和NiAl
2
O
4
,氧化膜厚度分别为8.78 μm、7.9 μm 和5.7 μm。O
2
流量为0 和10 sccm 涂层的氧化膜产生明显分层,其中上层为NiAl
2
O
4
,下层为α–Al
2
O
3
;而流量为20 sccm 涂层的氧化膜并没有发生明显分层。O 掺杂量的增加能够抑制氧化膜中大颗粒状Y–Al 氧化物夹杂的形成,降低氧化膜的生长速率。此外,氧化后未掺杂氧的涂层较含氧涂层退化严重,主要归因于氧掺杂涂层中弥散分布的氧化物颗粒抑制了涂层的退化。
The effect of oxygen doping content on the oxidation resistance of NiCrAlYN nano-cermet coatings at 1100 ℃ was investigated. Three coatings with different oxygen doping were prepared by multi-arc ion plating with O
2
flow rates at 0
10 sccm
and 20 sccm
respectively. After high-temperature at 1100 ℃ for 300 h
α–Al
2
O
3
and NiAl
2
O
4
were formed on the surface of three coatings. The thickness of the oxide scales was 8.78 μm
7.9 μm
and 5.7 μm
respectively. The oxide scales of the coatings deposited at 0 and 10 sccm showed significant delamination with the upper la
yer of NiAl
2
O
4
and the inner layer of α–Al
2
O
3
while this was not observed on the coating deposited at 20 sccm. The increase of oxygen doping content in nano cermets could effectively inhibit the formation of large particles of Y–Al oxide contaminant in the oxide scales and thus decrease the growth rate of the oxide scales. After oxidation
the oxygen containing coatings degraded more slowly than that without oxygen doping
which is mainly attributed to the beneficial effect of dispersed oxide particles in oxygen containing coatings on inhibiting the degradation of the coatings.
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