国网山西省电力公司超高压输电分公司,太原,030021
纸质出版:2023
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董凯,薛志宏,卢自强,何鹏杰,李杰,卢自英,茹海波. 多级次改性SiO2/PU超疏水涂层的制备及应用[J]. 航空制造技术, 2023, 66(15): 125-. DONG Kai, XUE Zhihong, LU Ziqiang, HE Pengjie, LI Jie, LU Ziying, RU Haibo. Preparation and Application of Hierarchical Modified SiO2/PU Superhydrophobic Coatings[J]. Aeronautical Manufacturing Technology, 2023, 66(15): 125-.
DONG Kai, XUE Zhihong, LU Ziqiang, et al. Preparation and Application of Hierarchical Modified SiO/PU Superhydrophobic Coatings[J]. Aeronautical Manufacturing Technology, 2023, 66(15).
董凯,薛志宏,卢自强,何鹏杰,李杰,卢自英,茹海波. 多级次改性SiO2/PU超疏水涂层的制备及应用[J]. 航空制造技术, 2023, 66(15): 125-. DONG Kai, XUE Zhihong, LU Ziqiang, HE Pengjie, LI Jie, LU Ziying, RU Haibo. Preparation and Application of Hierarchical Modified SiO2/PU Superhydrophobic Coatings[J]. Aeronautical Manufacturing Technology, 2023, 66(15): 125-. DOI: 10.16080/j.issn1671-833x.2023.15.125.
DONG Kai, XUE Zhihong, LU Ziqiang, et al. Preparation and Application of Hierarchical Modified SiO/PU Superhydrophobic Coatings[J]. Aeronautical Manufacturing Technology, 2023, 66(15). DOI: 10.16080/j.issn1671-833x.2023.15.125.
为了消除航空飞行器表面、电力传输电缆、风力涡轮机叶片等因低温结冰而带来的不利影响,同时为了增强航空飞行器表面吸波涂层的自清洁能力,将经过硅烷偶联剂改性的纳米二氧化硅(n-SiO
2
)和微米二氧化硅(m-SiO
2
)填料按照质量比6∶1 共混后与聚氨酯(PU)基体复合制得多级次改性SiO
2
/PU 超疏水涂层。研究表明,m-SiO
2
在PU 基体中较好的分散状态提升了涂层的稳定性,有效消除了因n-SiO
2
团聚而出现的涂层开裂现象。n-SiO
2
和m-SiO
2
填料在涂层的表面共同构筑起致密的多级次微凸起疏水结构,可以截留更多的空气来增大水滴的气–液接触面积。多级次改性SiO
2
/PU 超疏水涂层的水接触角可达158.56°±1.08°,并且具有良好的自清洁能力和耐磨性。此外,多级次改性SiO
2
/PU 超疏水涂层优秀的透波性能使其不会对吸波涂层的性能产生不利影响,表明制备的多级次改性SiO
2
/PU 超疏水涂层是一种理想的吸波材料保护涂层。
In order to eliminate the adverse effects of low-temperature icing on the surfaces of aerospace vehicles
power transmission cables
wind turbine blades
etc.
and to enhance the self-cleaning capability of the absorbing coatings on the surfaces of aerospace vehicles
modified hierarchical SiO
2
/PU superhydrophobic coating was produced by compounding nano-silicon dioxide (n-SiO
2
) and micron-silicon dioxide (m-SiO
2
) fillers modified by silane coupling agent with polyurethane (PU) matrix in a 6∶1 mass ratio. The results
show that the better dispersion of m-SiO
2
in the PU matrix improves the stability of the coating and effectively eliminates the cracking of the coating due to the agglomeration of n-SiO
2
. The n-SiO2 and m-SiO
2
fillers work together on the surface of the coating to build up a dense hierarchical micro-bulge hydrophobic structure
which can trap more air to increase the air–liquid contact area of water droplets. The water contact angle of the hierarchical modified SiO
2
/PU superhydrophobic coating can reach 158.56°±1.08° and has good self-cleaning ability and wear resistance. In addition
the excellent wavetransparent property of the hierarchical modified SiO
2
/PU superhydrophobic coating does not adversely affect the performance of the absorbing coating. It is shown that the prepared hierarchical modified SiO
2
/PU superhydrophobic coating is an ideal protective coating for wave-absorbing materials.
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