1. 中航工业成都飞机工业(集团)有限责任公司,成都,610092
2. 中国航空制造技术研究院高能束流加工技术国家级重点实验室,北京,100024
3. 中国航空制造技术研究院先进表面工程技术航空科技重点实验室,北京,100024
纸质出版:2025
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潘峰,王涛,贾东旭,马国佳,刘星,崔向中,张昊泽. 钛合金“基体效应”对WC掺杂类金刚石碳涂层力学和摩擦磨损性能的影响[J]. 航空制造技术, 2025, 68(13): 84-92.
PAN Feng, WANG Tao, JIA Dongxu, MA Guojia, LIU Xing, CUI Xiangzhong, ZHANG Haoze. Effect of Matrix Effect of Titanium Alloy on Mechanics and Frictional Properties of WC-Doped Diamond-Like Carbon Coatings[J]. Aeronautical Manufacturing Technology, 2025, 68(13): 84-92.
潘峰,王涛,贾东旭,马国佳,刘星,崔向中,张昊泽. 钛合金“基体效应”对WC掺杂类金刚石碳涂层力学和摩擦磨损性能的影响[J]. 航空制造技术, 2025, 68(13): 84-92. DOI: 10.16080/j.issn1671-833x.2025.13.084.
PAN Feng, WANG Tao, JIA Dongxu, MA Guojia, LIU Xing, CUI Xiangzhong, ZHANG Haoze. Effect of Matrix Effect of Titanium Alloy on Mechanics and Frictional Properties of WC-Doped Diamond-Like Carbon Coatings[J]. Aeronautical Manufacturing Technology, 2025, 68(13): 84-92. DOI: 10.16080/j.issn1671-833x.2025.13.084.
为了改善“软金属”摩擦磨损性能差的问题,采用中频磁控溅射技术在TC4-DT、TC21和TB17钛合金表面制备碳化钨(Tungsten carbide,WC)掺杂的类金刚石碳(Diamond-like carbon,DLC)涂层,设计了Ti/TiN/TiCN梯度过渡层并由多弧离子镀沉积方法完成制备,研究不同钛合金的“基体效应”对WC–DLC涂层力学性能和摩擦磨损性能的影响。通过SEM 和EDS观察分析了涂层表面形貌和化学元素分布,利用TEM 观察了涂层截面形貌及结构,使用XRD 和Raman 光谱表征了涂层结构,采用划痕仪和显微硬度计测试了涂层的结合强度、维氏硬度等力学性能,通过摩擦试验机和超景深显微镜测试摩擦磨损性能。结果显示,制备的3种钛合金,其涂层硬度比基体均提高了两倍以上。其中TC4-DT钛合金表面涂层硬度值最高,达到1566HV0.05;TB17钛合金表面涂层结合力最强,达到53 N以上,其摩擦磨损性能也最好,磨损率为0.593×10
–6
mm
3
·N
–1
·m
–1
,与基体相比,磨损率下降99.79% ;TC21钛合金表面涂层则表现出最大的摩擦系数、磨损深度和磨损率。以上结果表明,不同基体材料引发类金刚石涂层力学和膜基结合性能的差异,进而影响到涂层的摩擦磨损性能。
In order to improve the poor friction and wear properties of soft metal
tungsten carbide (WC)-doped diamond-like carbon (DLC) coatings were prepared on the surface of different TC4-DT
TC21 and TB17 titanium alloys by medium frequency magnetron sputtering technology. The Ti/TiN/TiCN gradient transition layer was designed and fabricated by multi-arc ion plating. The influence of the matrix effect of different titanium alloys on the mechanical properties and fri
ctional wear properties of WC– DLC coating was studied. The surface morphology and chemical element distribution of the coatings were analyzed by SEM and EDS
while the cross-sectional morphology and structure were observed by TEM
the structure of the coating was characterized by XRD and Raman spectra
and the mechanical properties such as bonding strength and Vickers hardness of the coating were tested by scratch tester and microhardness tester. Friction and wear prepared coating is more than two times higher than that of the three substrates
and the hardness of TC4-DT titanium alloy surface coating is the highest
reaching 1566HV0.05. The coating on TB17 titanium alloy has the strongest adhesion
whichis more than 53 N
and its friction and wear performance are also the best. The wear rate was 0.593×10
–6
mm
3
·N–1·m
–1
which is 99.79% lower than the substrate wear rate. However
the surface coating on TC21 titanium alloy shows the highest friction coefficient
the largest wear depth and wear rate among the three. The above results show that different substrate materials lead to differences in mechanical properties and bonding properties of diamond-like carbon coatings
which then affect the friction and wear properties of the coatings.
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