1. 中国科学院上海硅酸盐研究所,关键陶瓷材料全国重点实验室,上海,201899
2. 中国科学院大学, 材料科学与光电技术学院,北京,100049
纸质出版:2025
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赵伟玲, 王亮. 界面形貌对自修复热障涂层残余应力分布的影响[J]. 航空制造技术, 2025,68(18).
ZHAO Weiling, WANG Liang. Influence of Interface Morphology on Residual Stress Distribution of Self-Healing Thermal Barrier Coatings[J]. Aeronautical Manufacturing Technology, 2025, 68(18).
赵伟玲, 王亮. 界面形貌对自修复热障涂层残余应力分布的影响[J]. 航空制造技术, 2025,68(18). DOI: 10.16080/j.issn1671-833x.2025.18.062.
ZHAO Weiling, WANG Liang. Influence of Interface Morphology on Residual Stress Distribution of Self-Healing Thermal Barrier Coatings[J]. Aeronautical Manufacturing Technology, 2025, 68(18). DOI: 10.16080/j.issn1671-833x.2025.18.062.
在通过等离子喷涂制备自修复热障涂层时,由于喷涂喂料尺寸的不均匀性、雾化及融化状态、飞行轨迹以及在基材上铺展行为的差异,都会导致涂层内部以及不同层之间出现一定程度的起伏,自修复热障涂层界面处呈现不规则不均匀的几何结构特性,也进一步使得界面处应力分布不均,导致自修复热障涂层在随后的服役过程中容易发生翘曲或分层剥落失效。利用有限元软件模拟界面处微观形貌的改变对涂层内部及界面处残余应力的影响,建立余弦理想界面模型发现,当界面Ⅰ(陶瓷顶层与自修复层的界面)、界面Ⅱ(自修复层与粘结层的界面)的波长L增大时,界面Ⅰ、Ⅱ的最大S
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拉压应力都减小;当界面Ⅰ、Ⅱ的振幅A 增加时,应力同时受到界面粗糙度和界面缓冲应力的影响,残余应力不随A 的变化单调变化。改变上下界面波峰与波峰之间的相位偏移量d,探究界面交互作用的影响,界面Ⅰ的微观结构特征对界面Ⅱ波峰处的拉应力影响较大,当界面Ⅰ的波谷朝向界面Ⅱ的波峰时,这种形貌模式可以使界面Ⅱ的最大拉应力降低25.7%,避免界面产生过大的应力。依据界面处的应力状态,进一步系统探究了涂层的失效机理,为自修复热障涂层界面的优化调控及其加工工艺的优化设计提供更为全面的理论指导。
During the coating preparation process
differences in the morphology
size
molten state
flight path
and spreading behavior on the substrate of the feedstock result in a certain degree of undulation within and among the adjacent coating layers. Changes in the geometry of the interface of the coatings make the morphology at the interface more complex
showing irregular and inhomogeneous structural characteristics. It also further makes the stress distribution at the interface uneven
leading to unpredictable failure of the self-healing TBCs at the interface
in the subsequent service process
which in turn leads to the warpage or delamination failure of the entire coating. Finite element software was used to simulate the effect of the variation of the surface morphology on the residual stress which is inside the coating and at the interface. By establishing the cosine ideal interface model
it is found that when the wavelength L of interface Ⅰ and interface Ⅱ increases
both the maximum S
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tensile stress and compressive stress of interface Ⅰ and interface Ⅱ decrease. When the amplitude A of interfaces Ⅰ and Ⅱ increases
the stress is affected by both interface roughness and interface buffer stress. Varying the phase offset d between the peaks at the upper and lower interfaces
it is found that the microstructural characteristics of interface Ⅰ have a greater influence on the tensile stress at the peaks of interface Ⅱ . When the valley of interface I faces the peak of interface Ⅱ
this morphology pattern can reduce the maximum tensile stress of interface Ⅱ by 25.7% and avoid excessive stresses at interface Ⅱ. Further
the failure mechanism of the coating is systematically investigated
which provides a more comprehensive theoretical guidance for the optimal control of the interface of the self-healing thermal barrier coatings and the optimal design of the processing technology.
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