1. 中国航空制造技术研究院
2. 华南理工大学
3. 中国航空工业集团有限公司成都飞机设计研究所
纸质出版:2026-04-30
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刘时剑, 李琼云, 加晓宇, 等. SiC/SiC复合材料基体成分调控技术研究进展[J]. 航空制造技术, 2026,69(9):118-135.
LIU Shijian, LI Qiongyun, JIA Xiaoyu, et al. Research Progress on Matrix Composition Regulation of SiC/SiC Composites[J]. Aeronautical Manufacturing Technology, 2026, 69(9): 118-135.
刘时剑, 李琼云, 加晓宇, 等. SiC/SiC复合材料基体成分调控技术研究进展[J]. 航空制造技术, 2026,69(9):118-135. DOI: 10.16080/j.issn1671-833x.25020301.
LIU Shijian, LI Qiongyun, JIA Xiaoyu, et al. Research Progress on Matrix Composition Regulation of SiC/SiC Composites[J]. Aeronautical Manufacturing Technology, 2026, 69(9): 118-135. DOI: 10.16080/j.issn1671-833x.25020301.
连续碳化硅纤维增强碳化硅陶瓷基复合材料(SiC/SiC)是新一代航空航天热端部件的关键材料,但其在中温及高温下的抗氧化性能与耐久性仍面临挑战。本文系统综述了通过基体成分调控提升高温SiC/SiC复合材料抗氧化性能的研究进展,重点聚焦硼、铝、稀土及过渡金属基体元素改性策略的进展与优劣。从基体改性剂的引入方式与作用效果出发,详细对比了各种基体元素改性策略的核心机理、性能边界、工艺局限性与固有挑战。分析表明,硼改性在中温区(<1200℃)自愈合效率最高,但面临高温挥发瓶颈;铝改性通过稳定玻璃相将有效防护窗口拓展至1200~1400℃;稀土改性凭借其热匹配性在超高温区(>1300℃)潜力巨大,但面临纤维兼容性与水解挑战;过渡金属改性则提供了构筑超高温物理屏障的新思路。最后,本文指出未来研究应聚焦多元素协同设计、智能化低损伤制备与模型驱动的寿命预测三大方向,为实现SiC/SiC复合材料在极端环境下的长时可靠服役提供理论指导。
Continuous silicon carbide fiber-reinforced silicon carbide ceramic matrix composites (SiC/SiC) are key materials for new-generation aviation and aerospace hot-section components. However
their intermediate and high-temperature oxidation resistance and durability still face significant challenges. This paper systematically reviews recent research progress in enhancing the oxidation resistance of high-temperature SiC/SiC composites through matrix composition regulation
with a focus on four modification strategies based on boron
aluminum
rare earth
and transition metal elements. It provides an in-depth comparative analysis of these four types of technologies. The paper elaborates on the introduction methods and effectiveness of various modifiers and critically reviews their core mechanisms
performance boundaries
process limitations
and inherent challenges. Analysis indicates that boron modification offers the highest self-healing efficiency in the intermediate temperature range (<1200 ℃) but faces limitations due to volatility at high temperatures. Aluminum modification extends the effective protection window to 1200 – 1400 ℃ by stabilizing the glass phase. Rare earth modification holds great potential in the ultra-high temperature regime (>1300 ℃) due to its excellent thermal compatibility
yet encounters challenges related to fiber compatibility and hydrolytic stability. Transition metal modification offers a novel approach for constructing ultra-high-temperature physical barriers. Finally
the paper identifies three key future research directions: Multi-element synergistic design
intelligent low-damage manufacturing
and modeldriven lifetime prediction. The aim is to provide theoretical guidance for achieving the long-term
reliable service of SiC/SiC composites in extreme environments.
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